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4) Conclusion quantum different types of potassium ions provides a dependable theoretical hypothesis to reveal the main ambiguity behind PLP.A new hexa-nuclear Cu(II) complex [Cu3(μ2-1κNO2,2κNO2-L)(μ-Cl)2(Cl)(MeOH)(DMF)2]2 (1), where H4L = N'1,N'2-bis(2-hydroxybenzylidene)oxalohydrazide, was synthesized and totally described as IR spectroscopy, ESI-MS, elemental evaluation, and single crystal X-ray diffraction. Hard 1 and the dinuclear oxidovanadium(V) one [2(1κNO2,2κNO2-L)]·2